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Екатерина Калиниченко

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  • О себе:There are numerous mathematically equivalent formulations of quantum mechanics. One of the oldest and most commonly used formulations is the transformation theory proposed by Cambridge theoretical physicist Paul Dirac, which unifies and generalizes the two earliest formulations of quantum mechanics, matrix mechanics (invented by Werner Heisenberg)[2] and wave mechanics (invented by Erwin Schrödinger). In this formulation, the instantaneous state of a quantum system encodes the probabilities of its measurable properties, or "observables". Examples of observables include energy, position, momentum, and angular momentum. Observables can be either continuous (e.g., the position of a particle) or discrete (e.g., the energy of an electron bound to a hydrogen atom). Generally, quantum mechanics does not assign definite values to observables. Instead, it makes predictions about probability distributions; that is, the probability of obtaining each of the possible outcomes from measuring an observable. Naturally, these probabilities will depend on the quantum state at the instant of the measurement. There are, however, certain states that are associated with a definite value of a particular observable. These are known as "eigenstates" of the observable ("eigen" can be roughly translated from German as inherent or as a characteristic). In the everyday world, it is natural and intuitive to think of everything being in an eigenstate of every observable. Everything appears to have a definite position, a definite momentum, and a definite time of occurrence. However, quantum mechanics does not pinpoint the exact values for the position or momentum of a certain particle in a given space in a finite time; rather, it only provides a range of probabilities of where that particle might be. Therefore, it became necessary to use different words for (a) the state of something having an uncertainty relation and (b) a state that has a definite value. The latter is called the "eigenstate" of the property being measured. For example, consider a free particle. In quantum mechanics, there is wave-particle duality so the properties of the particle can be described as a wave. Therefore, its quantum state can be represented as a wave, of arbitrary shape and extending over all of space, called a wave function. The position and momentum of the particle are observables. The Uncertainty Principle of quantum mechanics states that both the position and the momentum cannot simultaneously be known with infinite precision at the same time. However, one can measure just the position alone of a moving free particle creating an eigenstate of position with a wavefunction that is very large at a particular position x, and almost zero everywhere else. If one performs a position measurement on such a wavefunction, the result x will be obtained with almost 100% probability. In other words, the position of the free particle will almost be known. This is called an eigenstate of position (mathematically more precise: a generalized eigenstate (eigendistribution) ). If the particle is in an eigenstate of position then its momentum is completely unknown. An eigenstate of momentum, on the other hand, has the form of a plane wave. It can be shown that the wavelength is equal to h/p, where h is Planck's constant and p is the momentum of the eigenstate. If the particle is in an eigenstate of momentum then its position is completely blurred out. Usually, a system will not be in an eigenstate of whatever observable we are interested in. However, if one measures the observable, the wavefunction will instantaneously be an eigenstate (or generalized eigenstate) of that observable. This process is known as wavefunction collapse. It involves expanding the system under study to include the measurement device, so that a detailed quantum calculation would no longer be feasible and a classical description must be used. If one knows the corresponding wave function at the instant before the measurement, one will be a
  • День рождения:31.8.1983 (41 год)
  • Сейчас живёт в:Россия, Владивосток
  • Родной город:Владивосток
  • Политические взгляды:ультраконсервативные
  • Религиозные взгляды:не верю

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    The word “quantum” came from the Latin word which means "unit of quantity". In quantum mechanics, it refers to a discrete unit that quantum theory assigns to certain physical quantities, such as the energy of an atom at rest (see Figure 1, at right). The discovery that waves have discrete energy packets (called quanta) that behave in a manner similar to particles led to the branch of physics that deals with atomic and subatomic systems which we today call quantum mechanics. It is the underlying mathematical framework of many fields of physics and chemistry, including condensed matter physics, solid-state physics, atomic physics, molecular physics, computational chemistry, quantum chemistry, particle physics, and nuclear physics. The foundations of quantum mechanics were established during the first half of the twentieth century by Werner Heisenberg, Max Planck, Louis de Broglie, Albert Einstein, Niels Bohr, Erwin Schrödinger, Max Born, John von Neumann, Paul Dirac, Wolfgang Pauli and others. Some fundamental aspects of the theory are still actively studied.

    Quantum mechanics is essential to understand the behavior of systems at atomic length scales and smaller. For example, if Newtonian mechanics governed the workings of an atom, electrons would rapidly travel towards and collide with the nucleus, making stable atoms impossible. However, in the natural world the electrons normally remain in an unknown orbital path around the nucleus, defying classical electromagnetism.

    Quantum mechanics was initially developed to provide a better explanation of the atom, especially the spectra of light emitted by different atomic species. The quantum theory of the atom was developed as an explanation for the electron's staying in its orbital, which could not be explained by Newton's laws of motion and by Maxwell's laws of classical electromagnetism.

    In the formalism of quantum mechanics, the state of a system at a given time is described by a complex wave function (sometimes referred to as orbitals in the case of atomic electrons), and more generally, elements of a complex vector space. This abstract mathematical object allows for the calculation of probabilities of outcomes of concrete experiments. For example, it allows one to compute the probability of finding an electron in a particular region around the nucleus at a particular time. Contrary to classical mechanics, one can never make simultaneous predictions of conjugate variables, such as position and momentum, with arbitrary accuracy. For instance, electrons may be considered to be located somewhere within a region of space, but with their exact positions being unknown. Contours of constant probability, often referred to as “clouds” may be drawn around the nucleus of an atom to conceptualize where the electron might be located with the most probability. It should be stressed that the electron itself is not spread out over such cloud regions. It is either in a particular region of space, or it is not[citation needed]. Heisenberg's uncertainty principle quantifies the inability to precisely locate the particle.

    The other exemplar that led to quantum mechanics was the study of electromagnetic waves such as light. When it was found in 1900 by Max Planck that the energy of waves could be described as consisting of small packets or quanta, Albert Einstein exploited this idea to show that an electromagnetic wave such as light could be described by a particle called the photon with a discrete energy dependent on its frequency. This led to a theory of unity between subatomic particles and electromagnetic waves called wave–particle duality in which particles and waves were neither one nor the other, but had certain properties of both. While quantum mechanics describes the world of the very small, it also is needed to explain certain “macroscopic quantum systems” such as superconductors and superfluids.

    Broadly speaking, quantum mechanics incorporates four classes of phenomena that classical physics cannot account for: (i) the

Опыт работы и образование

  • Школа № 23'00
  • 1990–2000
  • Класс: а
  • Владивосток

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